Harnessing the sun’s energy to generate electricity could be the answer to the world’s growing demand, but only if the process is commercially viable. Researchers from KAUST are trying to streamline the manufacture of more efficient and versatile alternatives to conventional silicon solar cells.
Colloidal quantum dots – tiny semiconductor crystals that can capture and convert light into electrical energy – are attracting a lot of research interest because their size allows them to be fabricated like an ink on to a flexible surface cheaply and easily. Yet efficiency and production issues still limit their potential.
“The ability to use quantum dots to harvest the near-infrared of the solar spectrum opens new opportunities to generate electricity while also managing heat, both of which are particularly welcome in Saudi Arabia,” explains Aram Amassian from KAUST's Solar and Photovoltaic Engineering Research Center.
These quantum dots – due to quantum effects related to their small size – are much better at absorbing light than regular layers of semiconductors. However at less than 10 per cent, their power conversion efficiency is fairly poor, and the dozens of manual steps required to fabricate the light-absorbing layer makes them very expensive to manufacture.
So Amassian’s team, along with collaborators from the University of Toronto in Canada, tried to find a streamlined method to fabricate quantum dot solar cells to make them more commercially viable.
One recent breakthrough had been to introduce organic ligand molecules which drew the quantum dots very closely together to allow electrical charges to be transported across the solar cell. This process used a solvent, methanol, to deliver the ligand molecules into the solar cell. However if the quantum dots were exposed to the solvent for too long, they were chemically damaged and required labor-intensive, repetitive and wasteful procedures to fix.
To look for efficiency gains Amassian’s team focused on the solvent. They showed by switching to a more neutral, organic solvent, acetonitrile, the performance of the solar cells improved considerably. Use of the milder solvent also meant that thicker layers of quantum dots could be treated with ligands without compromising efficiency.
Development of quantum dot solar cells still has a long way to go, but such advances in performance and fabrication suggest that new technologies are possible beyond the conventional solar cells now found on rooftops, says Amassian. “These lessons will be crucial in the development of solution-processed, semi-transparent quantum dot solar cells, which can be integrated into windows, buildings and transportation infrastructure in sunny and warm climates."
Kirmani, A. R., Carey, G., Abdelsame, M., Yan, B., Cha, D. et al. Effect of solvent environment on colloidal-quantum-dot solar-cell manufacturability and performance. Advanced Materials 26, 4717–4723 (2014). | article