An organic semiconductor photocatalyst that significantly enhances the generation of hydrogen gas could lead to more efficient energy storage technologies.
The combustion of fossil fuels is leading to dangerous climate change, driving the search for cleaner renewable energy sources. Solar energy is by far the most abundant renewable energy source, but unlocking its potential requires a way to store it for later use.
A standard method for storing solar energy is in the chemical bonds of molecular hydrogen using hydrogen evolution photocatalysts (HEPs). Currently, most HEPs are made from single-component inorganic semiconductors. These can only absorb light at ultraviolet wavelengths, which limits their ability to produce hydrogen.
A team led by Iain McCulloch from the KAUST Solar Center, in partnership with researchers from the United States and the United Kingdom, has now developed HEPs made from two different semiconducting materials. They incorporated these materials into organic nanoparticles that can be tuned to absorb more of the visible light spectrum.
“Traditionally, inorganic semiconductors have been used for photocatalytic applications,” says Jan Kosco, first author of the study. “However, these materials absorb primarily UV light, which comprises less than five percent of the solar spectrum. Therefore, their efficiency is limited.”
The team first used a method called miniemulsion, in which a solution of the organic semiconductors is emulsified in water with the aid of a stabilizing surfactant. Next, they heated the emulsion to drive off the solvent, leaving behind surfactant-stabilized organic semiconductor nanoparticles.
By varying the surfactant, they were able to control the structure of the nanoparticles, transforming them from a core-shell structure to a mixed donor-acceptor structure. The blended structure allowed them to introduce a heterojunction between the layers of the donor polymer and nonfullerene acceptor.
“Both structures absorb light at the same rate,” explains Kosco, “but in the core-shell structure, only photogenerated holes reach the surface; however, in the mixed structure, both holes and electrons reach the surface of the nanoparticles, resulting in enhanced generation of hydrogen.
The HEPs exhibited hydrogen evolution rates an order of magnitude beyond what is currently achievable with single-component inorganic HEPs. This lays the foundation for next-generation energy storage technologies.
“We are currently studying the performance of nanoparticles formed from different blends of semiconductors to better understand their structure-activity relationships,” says McCulloch. “We are looking to design nanoparticle photocatalysts for other photocatalytic reactions, such as oxygen evolution or carbon dioxide reduction.”
- Kosco, J., Bidwell, M, Hyojung, C., Tyler, M., Howells, C.T., Sachs, M., Anjum, D.H., Lopez, S.G., Zou, L., Zhan, L., Tellam, J., Sougrat, R., Laquai, F., Delongchamp, D.M., Durrant, J.R. & McCulloch, I. Enhanced photocatalytic hydrogen evolution from organic semiconductor heterojunction nanoparticles. Nature Materials 19, 559–565 (2020).| article