A method to nanoengineer an emerging family of semiconductors known as perovskites could reduce the cost of high-performance optoelectronic devices.
The properties of a semiconductor can be controlled by nanoscale engineering using technologies that slowly deposit atoms on a substrate. These methods are expensive and limited to conventional semiconductor materials, motivating scientists to search for new methods.
Quantum wells are semiconductor films of just a few nanometers, sandwiched between two thicker layers of a different semiconducting material. An energy barrier between the two materials blocks the electrical charge carriers from leaving the well layer, effectively limiting their motion to two dimensions. This radically alters the well material’s properties, making them more optically active, for example. This effect can be amplified further by combining multiple quantum wells into a single stack.
Epitaxial methods—depositing crystalline film on a crystalline substrate—are used to construct such stacks from gallium arsenide or gallium nitride by expensive processes with specialized equipment. But, another more practical approach is needed if this multiple quantum well architecture is to be used in perovskite devices. “Metal halide perovskites have excellent energy conversion efficiency for light harvesting and photoluminescence,” says postdoc Kwang Jae Lee from Osman Bakr’s Lab in the KAUST Catalyst Center. Quantum wells could improve this efficiency still further.
Working with colleagues from across KAUST and in collaboration with researchers from Korea, Bakr, Lee and team created perovskite multiple quantum wells using a simple technique known as thermal evaporation. They started with powders of their chosen perovskite well material, CsPbBr3, and a barrier material, TPBi. These powders evaporated when heated in a vacuum chamber, and the vapor particles traveled to a substrate where they formed a film. The team alternated between heating the TPBi and the CsPbBr3 to make their quantum wells.
Key to their success was calibration of the deposition rate. The team optimized the evaporation rates of their CsPbBr3 and TPBi powders at 0.015 and 0.020 nanometers per second, respectively. Unlike most epitaxial technologies, thermal evaporators are simple and widely available. Moreover, epitaxial methods need a substrate with a similar atomic lattice spacing to that of the deposited layer. The evaporation method, however, is applicable to any substrate; Lee and the team used simple glass because of the defect tolerance of perovskite materials.
“I think this is just the beginning,” says Lee. “The study points in one unexplored direction in perovskite research, and we expect further exciting perovskite devices based on this work in the near future.”
Lee, K. J, Turedi, B., Sinatra, L., Zhumekenov, A. A. Maity, P. Dursun, I., Naphade, R., Merdad, N., Alsalloum, A., Oh, S., Wehbe, N., Hedhill, M., Kang, C.H., Subedi, R.C., Cho, N., Kim, J.S., Ooi, B., Mohammed, O.F. & Bakr, O.M. Perovskite-based artificial multiple quantum wells. Nano Letters 6, 3535-3542 (2019).| article