New methods of arranging silver nanowires make them more durable, shows a study by KAUST. These nanowires form flexible, transparent conductive layers that can be used for improved solar cells, strain sensors and next-generation mobile phones.
Applying nanotechnology in electronic devices requires rigorous testing of individual tiny components to ensure that they will stand up to use. Silver nanowires show great promise as connectors that could be arranged in flexible, near-transparent meshes for touchscreens or solar cells, but it is unclear how they will respond to prolonged stresses from bending and carrying current.
Testing the bulk properties of a large sample of nanoparticles is easy, but not completely revelatory. However, adopting transmission electron microscopy (TEM) makes it possible to examine individual nanoparticles. Ph.D. student Nitin Batra and his supervisor Pedro Costa are at the forefront of developing new TEM techniques. This has allowed them to study single silver nanowires in detail1.
“A major part of our work has been designing and fabricating sample platform prototypes (or 'chips') for TEM, which allow us to characterize and manipulate nanomaterials with an unsurpassed spatial resolution,” says Batra.
To improve on expensive commercially available chips that contain a very fragile membrane to support nanoparticles, Batra and Costa, with help from Ahad Syed of the Nanofabrication Core Lab at KAUST, have now submitted to patenting2 their own robust, reusable chips that do not require a membrane.
The researchers suspended silver nanowires from platinum electrodes over their custom-made TEM chips and applied a range of voltages until the nanowires failed due to heating by the electrical current. They found that straight nanowires tended to snap when they reached a certain high current density, at points determined by local structural defects.
More interesting behavior was seen when the nanowires were bent from the beginning. These samples tended to buckle instead of snapping at high voltage and exhibited an ability to self-heal because they remained held together by the carbon coating on the outside of the wires. Some nanowires even exhibited resonant vibrations, like the harmonics on a guitar string, before they failed.
“Many devices are expected to undergo repeated bending and twisting by the end-user, which means that it is not realistic to limit the study of the electrical response of silver nanowires to straight configurations,” says Batra. “Our results suggest that the failure rate of such devices could be minimized by using bent nanowires instead of straight ones. The self-healing capability could effectively delay the breakdown of the circuit.”
Batra, N.M., Syed, A. & Costa, P.M.F.J. Current-induced restructuring in bent silver nanowires. Nanoscale 11, 3606-3618 (2019).| article
- US provisional patent 62/677,333. Patentees: Nitin M. Batra, Pedro M.F.J. Costa. Title “Membraneless platform for correlated analysis of nanomaterials” (2019).